In-situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N
Bull, DJ, Sorbic, N, Moser, D, Telling, M.T.F, Smith, R.I., Gregory, D.H. and Ross, DK 2011, 'In-situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N' , Faraday Discussions, 151 .
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The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a nonstoichiometric Li4_2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4_2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.
|Additional Information:||Reproduced by permission of The Royal Society of Chemistry|
|Schools:||Colleges and Schools > College of Science & Technology > School of Computing, Science and Engineering > Materials & Physics Research Centre|
Colleges and Schools > College of Science & Technology
Colleges and Schools > College of Science & Technology > School of Computing, Science and Engineering
|Journal or Publication Title:||Faraday Discussions|
|Publisher:||Royal Society of Chemistry|
|Depositing User:||Prof D. Keith Ross|
|Date Deposited:||22 Jun 2011 09:59|
|Last Modified:||31 Dec 2011 01:38|
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