Skip to the content

In-situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N

Bull, DJ, Sorbic, N, Moser, D, Telling, M.T.F, Smith, R.I., Gregory, D.H. and Ross, DK 2011, 'In-situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N' , Faraday Discussions, 151 .

[img]
Preview
PDF - Submitted Version
Download (281kB) | Preview

Abstract

The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a nonstoichiometric Li4_2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4_2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.

Item Type: Article
Additional Information: Reproduced by permission of The Royal Society of Chemistry
Themes: Energy
Schools: Colleges and Schools > College of Science & Technology > School of Computing, Science and Engineering > Materials & Physics Research Centre
Colleges and Schools > College of Science & Technology
Colleges and Schools > College of Science & Technology > School of Computing, Science and Engineering
Journal or Publication Title: Faraday Discussions
Publisher: Royal Society of Chemistry
Refereed: Yes
ISSN: 1359-6640
Depositing User: Prof D. Keith Ross
Date Deposited: 22 Jun 2011 08:59
Last Modified: 04 Jun 2014 07:29
URI: http://usir.eprints.org/id/eprint/16479

Actions (login required)

Edit record (repository staff only) Edit record (repository staff only)

Downloads

Downloads per month over past year