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In-situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N

Bull, DJ, Sorbic, N, Moser, D, Telling, M.T.F, Smith, R.I., Gregory, D.H. and Ross, DK 2011, 'In-situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N' , Faraday Discussions, 151 .

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    Abstract

    The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a nonstoichiometric Li4_2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4_2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.

    Item Type: Article
    Additional Information: Reproduced by permission of The Royal Society of Chemistry
    Themes: Energy
    Schools: Colleges and Schools > College of Science & Technology > School of Computing, Science and Engineering > Materials & Physics Research Centre
    Colleges and Schools > College of Science & Technology
    Colleges and Schools > College of Science & Technology > School of Computing, Science and Engineering
    Journal or Publication Title: Faraday Discussions
    Publisher: Royal Society of Chemistry
    Refereed: Yes
    ISSN: 1359-6640
    Depositing User: Prof D. Keith Ross
    Date Deposited: 22 Jun 2011 09:59
    Last Modified: 20 Aug 2013 17:58
    URI: http://usir.salford.ac.uk/id/eprint/16479

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