An in situ neutron diffraction measurement of the pressure-dependent evolution of a MgD2: TiD2 mixture.
Moser, D, Bull, DJ, Cowpe, JS, Roach, D, Noreus, D and Tucker , M 2010, 'An in situ neutron diffraction measurement of the pressure-dependent evolution of a MgD2: TiD2 mixture.' , High Pressure Research, 30 (4) , pp. 643-654.Full text not available from this repository. (Request a copy)
The hydrogen storage capacity of Mg–Ti–H films is approximately five times that of conventional metal hydride electrodes in NiMH-batteries. Mg and Ti are considered to be immiscible in the bulk and the ambient pressure phase diagram of Mg and Ti indicates that no binary stable bulk compounds are formed. However, in the presence of hydrogen, an Mg–Ti–H phase has been obtained by Kyoi et al. using a high pressure synthesis – where magnesium hydride is compacted with different TM-hydrides in an anvil cell at pressures of the order several GPa (4–8 GPa) and at a temperature of 873 K. In this work, we have proved the feasibility of in situ powder diffraction using the Paris–Edinburgh high pressure cell for the observation of structural changes on this system and we propose modifications to improve the output of the experiment.
|Schools:||Colleges and Schools > College of Science & Technology > School of Computing, Science and Engineering > Materials & Physics Research Centre|
|Journal or Publication Title:||High Pressure Research|
|Publisher:||Taylor & Francis|
|Depositing User:||Prof D. Keith Ross|
|Date Deposited:||23 Apr 2012 11:46|
|Last Modified:||20 Aug 2013 17:58|
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