Wilkinson, JA, Rossington, SB, Ducki, S, Leonard, J and Hussain, N 2006, 'Asymmetric alkylation of diarylmethane derivatives' , Tetrahedron, 62 (8) , pp. 1833-1844.

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Abstract

Deprotonation–alkylation of prochiral diarylmethane substrates using sec-BuLi and (−)-sparteine has been carried out in excellent yields and up to 94% ee. A variety of enantioselective alkylations, silylations and stannylations have been performed on four different diarylmethanes. Surrogates for (+)-sparteine have also been applied in this study including a novel surrogate.

Item Type:	Article
Uncontrolled Keywords:	Asymmetric, alkylation, diarylmethane, sparteine
Themes:	Subjects / Themes > Q Science > Q Science (General) Subjects / Themes > Q Science > QD Chemistry Subjects outside of the University Themes
Schools:	Colleges and Schools > College of Science & Technology Colleges and Schools > College of Science & Technology > School of Environment and Life Sciences Colleges and Schools > College of Science & Technology > School of Environment and Life Sciences > Biomedical Research Centre
Journal or Publication Title:	Tetrahedron
Publisher:	Elsevier
Refereed:	Yes
ISSN:	00404020
Depositing User:	H Kenna
Date Deposited:	08 Aug 2007 15:24
Last Modified:	27 Sep 2011 12:21
URI:	http://usir.salford.ac.uk/id/eprint/191

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