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Hydrogenation reaction pathway in Li2Mg(NH)2

Weidner, E, Dolci, F, Hu, J, Lohstroh, W, Hansen, T, Bull, DJ and Fichtner, M 2009, 'Hydrogenation reaction pathway in Li2Mg(NH)2' , The Journal of Physical Chemistry C, 113 (35) , pp. 15772-15777.

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Abstract

Results of the first time-resolved in situ neutron diffraction measurements during absorption of deuterium in Li2Mg(ND)2 reveal the occurrence of a two-stage reaction. The first stage involves the reaction to LiND2, LiD, and Li2Mg2(ND)3, with the second stage leading to full deuteration to Mg(ND2)2 and LiD. Since no structural model for Li2Mg2(NH)3 exists in the literature, its structure has been determined from refinement of X-ray and neutron diffraction data. These new data provide key information toward the clarification of the hydrogenation mechanism in this system.

Item Type: Article
Schools: Schools > School of Computing, Science and Engineering > Salford Innovation Research Centre (SIRC)
Journal or Publication Title: The Journal of Physical Chemistry C
Publisher: ACS Publication
ISSN: 1932-7447
Related URLs:
Funders: Funder not known
Depositing User: Institutional Repository
Date Deposited: 07 Nov 2014 12:35
Last Modified: 29 Oct 2015 00:11
URI: http://usir.salford.ac.uk/id/eprint/32321

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