Skip to the content

Trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-kappa O-2,O ')bis(4-methyl-1,2,3-selenadiazole-kappa N-3)copper(II)

Boag, NM, Jackson, AD, Lickiss, PD, Pilkington, RD and Redhouse, AD 2010, 'Trans-Bis(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-kappa O-2,O ')bis(4-methyl-1,2,3-selenadiazole-kappa N-3)copper(II)' , Acta Crystallographica Section E : Structure Reports Online, 66 (2) , M241.

[img]
Preview
PDF - Published Version
Download (518kB) | Preview

Abstract

In the title compound, [Cu(C5HF6O2)(2)(C3H4N2Se)(2)], the Cu-II atom (site symmetry (1) over bar) is coordinated by two O,O'-bidentate 1,1,1,5,5,5-hexafluoro-2,4-pentanedione (hp) ligands and two 4-methyl-1,2,3-selenadiazole molecules, resulting in a slightly distorted trans-CuN2O4 octahedral geometry in which the cis angles deviate by less than 3 degrees from 90 degrees. The selenadiazole plane is canted at 73.13 (17)degrees to the square plane defined by the pentanedionate O atoms. The F atoms of one of the hp ligands are disordered over two sets of sites in a 0.66 (3):0.34 (3) ratio. There are no significant intermolecular interactions in the crystal.

Item Type: Article
Schools: Schools > School of Computing, Science and Engineering > Salford Innovation Research Centre (SIRC)
Journal or Publication Title: Acta Crystallographica Section E : Structure Reports Online
Publisher: International Union of Crystallography
Refereed: Yes
ISSN: 1600-5368
Related URLs:
Funders: Non funded research
Depositing User: NM Boag
Date Deposited: 14 Jul 2015 16:00
Last Modified: 29 Oct 2015 00:11
URI: http://usir.salford.ac.uk/id/eprint/35301

Actions (login required)

Edit record (repository staff only) Edit record (repository staff only)

Downloads

Downloads per month over past year