Asymmetric synthesis of diarylmethane derivatives by dynamic kinetic resolution
Gooch, LM, Rossington, SB and Wilkinson, JA 2015, 'Asymmetric synthesis of diarylmethane derivatives by dynamic kinetic resolution' , Tetrahedron Letters, 56 (26) , pp. 4025-4027.
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Asymmetric allylation of ortho-methoxydiphenylmethane has been carried out with high yields and ee of up to 94% using the chiral ligand (−)-sparteine as an additive. Results of reactions performed under various conditions suggest that a dynamic kinetic resolution of two rapidly interconverting diastereomeric complexes is occurring.
|Themes:||Subjects outside of the University Themes|
|Schools:||Schools > School of Environment and Life Sciences > Biomedical Research Centre|
|Journal or Publication Title:||Tetrahedron Letters|
|Depositing User:||JA Wilkinson|
|Date Deposited:||01 Jul 2015 11:57|
|Last Modified:||01 Jul 2015 11:57|
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