Preparation of thin and highly stable Pd/Ag composite membranes and simulative analysis of transfer resistance for hydrogen separation
Hou, K and Hughes, R 2003, 'Preparation of thin and highly stable Pd/Ag composite membranes and simulative analysis of transfer resistance for hydrogen separation' , Journal of Membrane Science, 214 (1) , pp. 43-55.
Full text not available from this repository. (Request a copy)Abstract
Composite Pd/Ag membranes supported on an alpha-alumina substrate have been prepared by sequential electroless plating and the morphology of the membranes has been examined by SEM and XRD analysis. SEM pictures revealed that the Pd/Ag film was of columnar form perpendicular to the substrate. Homogeneous alloy films of Pd/Ag were obtained by annealing the separate Pd and Ag deposited layers at temperatures higher than 600oC in a hydrogen atmosphere.Hydrogen fluxes of up to 0.35mol/(m2s) and hydrogen/nitrogen selectivities of 4500 were obtained and a long-term temperature cycling test showed no deterioration in membrane performance. A simulative analysis was carried out to investigate the effect of boundary layer and the distribution of hydrogen transfer resistance between the boundary layer, the Pd/Ag film and the substrate.
| Item Type: | Article |
|---|---|
| Themes: | Subjects / Themes > Q Science > QD Chemistry Subjects outside of the University Themes |
| Schools: | Colleges and Schools > College of Science & Technology Colleges and Schools > College of Science & Technology > School of Computing, Science and Engineering Colleges and Schools > College of Science & Technology > School of Computing, Science and Engineering > Materials & Physics Research Centre |
| Journal or Publication Title: | Journal of Membrane Science |
| Publisher: | Elsevier |
| Refereed: | Yes |
| ISSN: | 03767388 |
| Depositing User: | H Kenna |
| Date Deposited: | 03 Sep 2007 13:57 |
| Last Modified: | 27 Sep 2011 12:28 |
| URI: | http://usir.salford.ac.uk/id/eprint/371 |
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