In-situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N

Bull, DJ ORCID: https://orcid.org/0000-0001-9406-2031, Sorbic, N, Moser, D, Telling, M.T.F, Smith, R.I., Gregory, D.H. and Ross, DK 2011, 'In-situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N' , Faraday Discussions, 151 .

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Abstract

The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a nonstoichiometric Li4_2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4_2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.

Item Type:	Article
Additional Information:	Reproduced by permission of The Royal Society of Chemistry
Themes:	Energy
Schools:	Schools > School of Computing, Science and Engineering Schools > School of Computing, Science and Engineering > Salford Innovation Research Centre
Journal or Publication Title:	Faraday Discussions
Publisher:	Royal Society of Chemistry
Refereed:	Yes
ISSN:	1359-6640
Depositing User:	Prof D. Keith Ross
Date Deposited:	22 Jun 2011 08:59
Last Modified:	15 Feb 2022 15:55
URI:	https://usir.salford.ac.uk/id/eprint/16479

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