Asymmetric alkylation of diarylmethane derivatives

Wilkinson, JA ORCID: https://orcid.org/0000-0003-1300-6017, Rossington, SB, Ducki, S, Leonard, J and Hussain, N 2006, 'Asymmetric alkylation of diarylmethane derivatives' , Tetrahedron, 62 (8) , pp. 1833-1844.

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Abstract

Deprotonation–alkylation of prochiral diarylmethane substrates using sec-BuLi and (−)-sparteine has been carried out in excellent yields and up to 94% ee. A variety of enantioselective alkylations, silylations and stannylations have been performed on four different diarylmethanes. Surrogates for (+)-sparteine have also been applied in this study including a novel surrogate.

Item Type:	Article
Themes:	Subjects / Themes > Q Science > Q Science (General) Subjects / Themes > Q Science > QD Chemistry Subjects outside of the University Themes
Schools:	Schools > School of Environment and Life Sciences Schools > School of Environment and Life Sciences > Biomedical Research Centre
Journal or Publication Title:	Tetrahedron
Publisher:	Elsevier
Refereed:	Yes
ISSN:	00404020
Depositing User:	H Kenna
Date Deposited:	08 Aug 2007 14:24
Last Modified:	27 Aug 2021 21:59
URI:	https://usir.salford.ac.uk/id/eprint/191

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