Hydrogenation reaction pathway in Li2Mg(NH)2

Weidner, E, Dolci, F, Hu, J, Lohstroh, W, Hansen, T, Bull, DJ ORCID: https://orcid.org/0000-0001-9406-2031 and Fichtner, M 2009, 'Hydrogenation reaction pathway in Li2Mg(NH)2' , The Journal of Physical Chemistry C, 113 (35) , pp. 15772-15777.

[img] PDF - Published Version
Restricted to Repository staff only

Download (3MB) | Request a copy


Results of the first time-resolved in situ neutron diffraction measurements during absorption of deuterium in Li2Mg(ND)2 reveal the occurrence of a two-stage reaction. The first stage involves the reaction to LiND2, LiD, and Li2Mg2(ND)3, with the second stage leading to full deuteration to Mg(ND2)2 and LiD. Since no structural model for Li2Mg2(NH)3 exists in the literature, its structure has been determined from refinement of X-ray and neutron diffraction data. These new data provide key information toward the clarification of the hydrogenation mechanism in this system.

Item Type: Article
Schools: Schools > School of Computing, Science and Engineering > Salford Innovation Research Centre
Journal or Publication Title: The Journal of Physical Chemistry C
Publisher: ACS Publications
ISSN: 1932-7447
Related URLs:
Funders: Funder not known
Depositing User: Institutional Repository
Date Deposited: 07 Nov 2014 12:35
Last Modified: 15 Feb 2022 18:37
URI: https://usir.salford.ac.uk/id/eprint/32321

Actions (login required)

Edit record (repository staff only) Edit record (repository staff only)


Downloads per month over past year