Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells

Yates, HM ORCID: https://orcid.org/0000-0002-3261-0183, Meroni, MP, Raptis, D, Hodgkinson, JL and Watson, TM 2019, 'Flame assisted chemical vapour deposition NiO hole transport layers for mesoporous carbon perovskite cells' , J. Mater. Chem. C, 7 (42) , pp. 13235-13242.

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Abstract

Flame Assisted Chemical Vapour Deposition was utilised to directly deposit polycrystalline mesoporous NiO to enhance charge transport within carbon perovskite solar cells (C-PSC). This versatile technique is highly suited for deposition of large area thinfilms along with the ability to use simple, stable aqueous salts. The combination of low cost methods of screen printing and FACVD to produce the C-PSC make this an attractive route towards commercialisation. The effects of deposition parameters on the morphology, crystallinity and density of the deposited NiO are discussed, along with the importance of use of a low propane, ’lean flame’ on both the NiO and underlying F-doped tin oxide electrode. The thickness of the NiO layer was found to be critical in optimising the C-PSC efficiency. Addition of the NiO layer resulted in an increased short circuit current density (17.30 mA cm-2to 20.28 mA cm-2). At an estimated NiO thickness of 17 nm the average cell efficiency (10.73 %) surpassed that of the control sample (9.08 %) so confirming the promise of this technique.

Item Type: Article
Schools: Schools > School of Computing, Science and Engineering > Salford Innovation Research Centre
Journal or Publication Title: J. Mater. Chem. C
Publisher: Royal Society of Chemistry
ISSN: 2050-7526
Related URLs:
Funders: EU Horizon 2020, Engineering and Physical Sciences Research Council (EPSRC)
Depositing User: HM Yates
Date Deposited: 12 Aug 2019 08:26
Last Modified: 11 Nov 2019 09:45
URI: http://usir.salford.ac.uk/id/eprint/52001

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